About
Rubber
HISTORY
Central and South American natives
used caoutchouc, basic component of what we know today as rubber, to
make balls for play in 4th century BC. In 18th and in the beginning
of 19th century interest for caoutchouc in Europe started to grow, with
production of the first rubber products, e.g. rubber gloves. The first
rubber products lacked on thermal resistance. When exposed to high temperatures,
they became sticky.
In the year 1839 Charles Goodyear
unintentionally discovered that soft and sticky caoutchouc could be
changed in very elastic material - rubber - with heating and adding
of sulfur. That enabled continuous and rapid development of the rubber
industry.
Rubber products belong to the
group of products without we can hardly imagine modern world.
Present consumption of the caoutchouc
in the world rates at 15 million tons. About 38 % of natural caoutchouc
and 62 % of synthetic caoutchouc is refined all over the world. 50 %
of raw material base is used in the tires industry, another half for
other rubber products for mass consumption, health services, industry
etc.
PROPERTIES
The most important property
of rubber, which essentially differentiates it from other materials,
is its elasticity. For example, rubber band can be stretched out up
to 10 times of its original length, and it will keep the original length
after stretching.
Besides elasticity, rubber has
also another good properties, such as: small amortization, impermeability
for water and air, good performance in different solutions, acid resistance,
stability within 200 oC and capability to keep elasticity even under
-100 oC. Rubber can be also excellently combined with another materials,
e.g. metals. In that case, we merge the elasticity of rubber with firmness
of metal.
Properties of rubber products
depend on recipes, procedures of mixing components and production processes
of particular products.
TYPES AND PROPERTIES
OF RUBBER MIXTURES
Many different types of rubber
mixtures are used in rubber industry, according to the needs and demands
of the product itself.
Natural Caoutchouc
- NR (SMR)
Type 30 - 90 Shore A
NR Caoutchouc is water-, alcohol-, glycol-, silicon oil- and lubricant-resistant.
It is used for production of conveying belts, straps, membranes, gloves
etc.
Styrene - Butadiene Caoutchouc - SBR (Buna Huls
EM)
Type 35 - 95 Shore A
SBR Caoutchouc has similar mechanical properties as NR, but more resists
amortization, higher temperatures and aging. It loses elasticity on
lower temperatures. Two thirds of SBR sources are used for production
of tires, rest for cable sheathings, fittings, floor coverings etc.
Polynorbornensian
Caoutchouc - PNR (Norsorex)
Type 10 - 45 Shore A
Products made of PNR Caoutchouc are extraordinary soft and firm on the
same time.
They are used for making profiles, fittings and absorbers of sounds
and vibrations.
Chlorineprenic
Caoutchouc - CR (Bayprene, Neoprene)
Type 25 - 90 Shore A
CR Caoutchouc is fire-resistant and also resists weather influences
and aging. It is used for production of conveying belts, fittings, elastic
pipes, cable sheathings etc.
Butyl Caoutchouc
- IIR (Polysar - Butyl)
Type 30 - 80 Shore A
IIR Caoutchouc is impermeable for gases, acid- and ozone-resistant.
It has good electric properties and shows less amortization. It is used
for making tubes, fittings, membranes, cables etc.
Ethylene / Propylene
/ Diene Caoutchouc - EPDM (BUNA AP Keltan)
Type 30 - 90 Shore A
EPDM Caoutchouc resists heat and aggressive substances, is very constant,
slowly aging and high elastic. It is used in car industry for production
of soft tubes and cables.
Acrylnitril
/ Butadiene Caoutchouc - NBR (Perbunan Krynac)
Type 30 - 95 Shore A
NBR Caoutchouc resists gasoline, mineral oils and lubricants, but doesn't
resist aging. It is used for production of fittings, membranes, soft
pipes, conveying belts, cable sheathings and in shoe industry for shoe
soles, gloves etc.
Chloriensulfonic
Polyethylene Caoutchouc - CSM (Hypalon)
Type 45 - 90 Shore A
Mixtures based on CSM Caoutchouc are used for coatings (transparent
varnish). Otherwise it is used for production of fittings, membranes
etc.
Polyacrylic
Caoutchouc - ACM (Hycar Vamac)
Type 50 - 90 Shore A
ACM products are acid-, ozone-, and heat-resistant. They lose elasticity
on lower temperatures. Mixtures are used for making O-shaped rings etc.
Silicone Caoutchouc - VMQ (Silastic)
Type 30 - 85 Shore A
VMQ products have excellent properties. They are heat-, oxygen-, ozone-,
UV-resistant and keep their elasticity under low temperatures. Even
under temperature changes they keep their mechanical and electrical
characteristics.
It is used for production of fittings, soft pipes for hot air transportation,
pharmaceutical and medical products etc.
Polyurethane
Caoutchouc - AU / EU (Adiprene)
Type 55 - 90 Shore A
AU / EU characterizes small usage of material and mineral oil- and ozone-resistance.
They are used for fittings, valves in furniture industry and isolation
of inner parts of vehicles in car industry.
Epychlorine
- Hydrine Caoutchouc - CO, ECO (Herclor Hydrin)
Type 40 - 90 Shore A
CO or ECO products are mineral oil-, ozone- and aging-resistant. They
are impermeable for gases.
They are used for fittings, membranes, soft pipes, valve-coatings etc.
Klander, d.o.o.
Karlovška 19
1000 Ljubljana
Tel.: +386-1-421-40-00
Fax: +386-1-421-40-05
E-mail: info@klander.si